Barrier to complex formation in the hydrogen atom-chlorine molecule reaction
نویسندگان
چکیده
منابع مشابه
Hydrogen Atom-formaldehyde Reaction
where H-H-C and H-D-C are weak bonds and make a negligible contribution, leads to a value of -2 kcal. Therefore, E5-E2=1 kcal compared with the experimental value of 1.0 kcal. The preexponential factor for this pair of isotopic reactions can be calculated from the difference in the entropies of activation. Using the same loose complex as above and applying the expression derived by Bigeleisens ...
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The authors are indebted to Professor Charles Palache of Harvard University, Professor D. Jerome Fischer of the University of Chicago and Dr. T. L. Tanton of the Department of Mines of the Canadian Geological Survey, through whose efforts the rocks used in this investigation were obtained. 1 Rayleigh, Proc. Roy. Soc., 80, 575 (1908). 2Rayleigh, Nature, 123, 607 (1929). 3 See Harkins, P. R., 38,...
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ژورنال
عنوان ژورنال: Chemical Physics Letters
سال: 1971
ISSN: 0009-2614
DOI: 10.1016/0009-2614(71)85043-1